STRUCTURAL DESCRIPTION OF TRANSITION METAL-METALLOID GLASSES

Short-range Oder in Transition Metal-metalloid Glasses

Metal and metalloid biorecovery using fungi

Bioleaching is a proven bioprocess for metal recovery by solution from solid matrices, while a bioprecipitation or biomineralization approach is of potential for biorecovery from solution. Fungi can directly and indirectly mediate the formation of many kinds of minerals, including oxides, phosphates, carbonates and oxalates, as well as elemental forms of metals and metalloids such as Ag, Se and...

Amorphous to amorphous insulator-metal transition in GeSe3:Ag glasses

We study an insulator-metal transition in a ternary chalcogenide glass (GeSe3)1−xAgx for x = 0.15 and 0.25. The conducting phase of the glass is obtained by using gap sculpting [Prasai et al., Sci. Rep. 5, 15522 (2015)] and it is observed that the metallic and insulating phases have nearly identical density functional energies but have a conductivity contrast of ∼108. As such, we demonstrate an...

Transition metal-doped chalcogenide glasses for broadband near-infrared sources

In this paper we report the spectroscopic data for samples of 0.031% iron, 0.017% nickel, 0.01% chromium and 0.017% cobalt (molar) doped gallium lanthanum sulphide (GLS) glass. Photoluminescence (PL) with a full width half maximum (FWHM) of around 500 nm and peaking between 1120 nm and 1460 nm is observed when excited using wavelengths of 850 nm and 1064 nm. The emission lifetime for nickel-dop...

Structural, chemical and biological aspects of antioxidants for strategies against metal and metalloid exposure

Oxidative stress contributes to the pathophysiology of exposure to heavy metals/metalloid. Beneficial renal effects of some medications, such as chelation therapy depend at least partially on the ability to alleviate oxidative stress. The administration of various natural or synthetic antioxidants has been shown to be of benefit in the prevention and attenuation of metal induced biochemical alt...